form-row align-items-center
html bootstrap5 Sample
<form>
<div class="form-row align-items-center">
<div class="col-auto">
<label class="sr-only" for="inputName">氏名</label>
<input type="text" class="form-control mb-2" id="inputName" placeholder="氏名を入力">
</div>
<div class="col-auto">
<label class="sr-only" for="inputUsername">ユーザーネーム</label>
<div class="input-group mb-2">
<input type="text" class="form-control" id="inputUsername" placeholder="ユーザーネームを入力">
</div>
</div>
<div class="col-auto">
<div class="form-check mb-2">
<input type="checkbox" class="form-check-input" id="check">
<label class="form-check-label" for="check"> チェックする </label>
</div>
</div>
<div class="col-auto">
<button type="submit" class="btn btn-primary mb-2">送信</button>
</div>
</div>
</form>